@Article{BatistaRodOliPetBal:2022:FaSyPo,
author = "Batista, Aline Fontana and Rodrigues Siqueli, Aline Castilho and
Oliveira, Ana Paula Silva de and Petraconi, Gilberto and Baldan,
Maur{\'{\i}}cio Ribeiro",
affiliation = "{Instituto Nacional de Pesquisas Espaciais (INPE)} and {Instituto
Nacional de Pesquisas Espaciais (INPE)} and {Instituto Nacional de
Pesquisas Espaciais (INPE)} and {Instituto Tecnol{\'o}gico de
Aeron{\'a}utica (ITA)} and {Instituto Nacional de Pesquisas
Espaciais (INPE)}",
title = "Facile synthesis of polyaniline catalyzed by carbon fiber for
supercapacitor applications",
journal = "Synthetic Metals",
year = "2022",
volume = "289",
pages = "e117116",
month = "Sept.",
keywords = "Carbon fiber, Catalysis, Polyaniline, Polymerization.",
abstract = "Polyaniline (PAni) widely studied conductive polymer due to its
incredible versatility, electrical properties, and low cost. PAni
usually is produced by chemical or electrochemical synthesis.
However, these processes either generate a large amount of waste
or are expensive and produce a small amount. The catalytic system
incorporated into the PAni synthesis can be a strategic way to
develop clean and low-cost processes. Therefore, we propose a
synthesis of PAni catalyzed by carbon fiber (CF) reported for the
first time. The procedure is to immerse the CF in an aqueous
solution of aniline and H2SO4, at room temperature, in an open
flask. Tests were carried out to investigate the CF as a catalyst
and the molecular oxygen as an oxidant in the polymerization
reaction. The samples were characterized by scanning electron
microscopy, Raman spectroscopy, infrared spectroscopy, and X-ray
photoelectron spectroscopy. According to the analyses, the
reaction catalysts are heteroatoms on the fiber surface. Molecular
oxygen present in atmospheric air is the oxidant of the reaction.
The method is environmentally friendly, simple, and economical
route to produce a conductive form of PAni on carbon fiber. The
composite produced was evaluated as a possible electrode for a
supercapacitor, and presented interesting results for application
in energy storage devices.",
doi = "10.1016/j.synthmet.2022.117116",
url = "http://dx.doi.org/10.1016/j.synthmet.2022.117116",
issn = "0379-6779",
language = "en",
targetfile = "Facile synthesis of polyaniline catalyzed by carbon fiber for
supercapacitor applications.pdf",
urlaccessdate = "21 maio 2024"
}